The vertical distribution of iron stable isotopes in the North Atlantic near Bermuda

Seawater dissolved iron isotope ratios (δ^(56)Fe) have been measured in the North Atlantic near Bermuda. In a full-depth profile, seawater dissolved δ^(56)Fe is isotopically heavy compared to crustal values throughout the water column (δ^(56)Fe_(IRMM-014) = +0.30‰ to +0.71‰). Iron isotope ratios are relatively homogenous in the upper water column (between +0.30‰ to +0.45‰ above 1500 m), and δ^(56)Fe increases below this to a maximum of +0.71‰ at 2500 m, decreasing again to +0.35‰ at 4200 m. The δ^(56)Fe profile is very different from the iron concentration profile; in the upper water column [Fe] is variable while δ^(56)Fe is relatively constant, and in the deeper water column δ^(56)Fe varies while [Fe] remains relatively constant. The δ^(56)Fe profile is also not well correlated with other hydrographic tracers in the North Atlantic such as temperature, salinity, or the concentrations of oxygen, phosphate, silica, and CFC-11. The dissimilarity between δ^(56)Fe profiles and profiles of [Fe] and other hydrographic tracers shows that Fe isotope ratios provide a unique sort of information about ocean chemistry, and they suggest that Fe isotopes may therefore be a valuable new tool for tracing the global sources, sinks, and biogeochemical cycling of Fe

The "African humid period" and the record of marine upwelling from excess ^(230)Th in Ocean Drilling Program Hole 658C

Using a high-resolution ^(230)Th normalized record of sediment flux, we document the deglacial and Holocene history of North African aridity and coastal upwelling at Ocean Drilling Program Hole 658C. At both the end of the Younger Dryas and after the 8.2 ka event, there are significant drops in terrigenous accumulation at our site, indicating an increase in the monsoon moisture flux over Africa at this time. At 5.5 ka, there is an abrupt end to the “African humid period” and a return to stronger upwelling conditions. For carbonate and opal fluxes the ^(230)Th normalization completely changes the shape of each record based on percentage variations alone. This site is a clear example of how variations in one sediment component can obscure changes in the others, and it demonstrates the need for radionuclide measurements more generally in paleoceanography. By taking our new records and a large amount of previous data from this site we conclude that increases in African moisture are tightly coupled to decreases in coastal upwelling intensity

Global climate evolution during the last deglaciation

Deciphering the evolution of global climate from the end of the Last Glacial Maximum approximately 19 ka to the early Holocene 11 ka presents an outstanding opportunity for understanding the transient response of Earth’s climate system to external and internal forcings. During this interval of global warming, the decay of ice sheets caused global mean sea level to rise by approximately 80 m; terrestrial and marine ecosystems experienced large disturbances and range shifts; perturbations to the carbon cycle resulted in a net release of the greenhouse gases CO_2 and CH_4 to the atmosphere; and changes in atmosphere and ocean circulation affected the global distribution and fluxes of water and heat. Here we summarize a major effort by the paleoclimate research community to characterize these changes through the development of well-dated, high-resolution records of the deep and intermediate ocean as well as surface climate. Our synthesis indicates that the superposition of two modes explains much of the variability in regional and global climate during the last deglaciation, with a strong association between the first mode and variations in greenhouse gases, and between the second mode and variations in the Atlantic meridional overturning circulation

Changing atmospheric Δ^(14)C and the record of deep water paleoventilation ages

We propose a new calculation method to better estimate the deep water ventilation age from benthic-planktonic foraminifera ^(14)C ages. Our study is motivated by the fact that changes in atmospheric Δ^(14)C through time can cause contemporary benthic and planktonic foraminifera to have different initial Δ^(14)C values. This effect can cause spurious ventilation age changes to be interpreted from the geologic data. Using a new calculation method, ^(14)C projection ages, we recalculate the data from the Pacific Ocean. Contrary to previous results, we find that the Pacific intermediate and deep waters were about 600 years older than today at the last glacial maximum. In addition, there are possible signals of ventilation age change prior to ice sheet melting and at the Younger Dryas. However, the data are still too sparse to constrain these ventilation transients

Compound-Specific δ^(34)S Analysis of Volatile Organics by Coupled GC/Multicollector-ICPMS

We have developed a highly sensitive and robust method for the analysis of δ^(34)S in individual organic compounds by coupled gas chromatography (GC) and multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). The system requires minimal alteration of commercial hardware and is amenable to virtually all sample introduction methods. Isobaric interference from O_2^+ is minimized by employing dry plasma conditions and is cleanly resolved at all masses using medium resolution on the Thermo Neptune MC-ICPMS. Correction for mass bias is accomplished using standard−sample bracketing with peaks of SF6 reference gas. The precision of measured δ^(34)S values approaches 0.1‰ for analytes containing >40 pmol S and is better than 0.5‰ for those containing as little as 6 pmol S. This is within a factor of 2 of theoretical shot-noise limits. External accuracy is better than 0.3‰. Integrating only the center of chromatographic peaks, rather than the entire peak, offers significant gain in precision and chromatographic resolution with minimal effect on accuracy but requires further study for verification as a routine method. Coelution of organic compounds that do not contain S can cause degraded analytical precision. Analyses of crude oil samples show wide variability in δ^(34)S and demonstrate the robustness and precision of the method in complex environmental samples

Past ocean temperatures and coupled U/Th and ^(14)C measurements from deep-sea corals

Deep-sea corals are a unique archive in paleoceanography. They have large banded skeletons that allow for high resolution records and have a high uranium content allowing for accurate calendar ages independent of radiocarbon age measurements. One problem with using deep-sea corals for long records is that it is difficult to date a large numbers of corals accurately and precisely. Unlike sediment cores, fossil fields of corals have no inherent stratigraphy and each individual coral must be separately dated

Deep-sea corals : a new oceanic archive

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, 1998.Vita.Includes bibliographical references.by Jess F. Adins.Ph.D

A deep-sea coral record of North Atlantic radiocarbon through the Younger Dryas: Evidence for intermediate water/deepwater reorganization

Our record of Younger Dryas intermediate-depth seawater Δ^(14)C from North Atlantic deep-sea corals supports a link between abrupt climate change and intermediate ocean variability. Our data show that northern source intermediate water (∼1700 m) was partially replaced by (14)^C-depleted southern source water at the onset of the event, consistent with a reduction in the rate of North Atlantic Deep Water formation. This transition requires the existence of large, mobile gradients of Δ^(14)C in the ocean during the Younger Dryas. The Δ^(14)C water column profile from Keigwin (2004) provides direct evidence for the presence of one such gradient at the beginning of the Younger Dryas (∼12.9 ka), with a 100‰ offset between shallow (<∼2400 m) and deep water. Our early Younger Dryas data are consistent with this profile and also show a Δ^(14)C inversion, with 35‰ more enriched water at ∼2400 m than at ∼1700 m. This feature is probably the result of mixing between relatively well ^(14)C ventilated northern source water and more poorly ^(14)C ventilated southern source intermediate water, which is slightly shallower. Over the rest of the Younger Dryas our intermediate water/deepwater coral Δ^(14)C data gradually increase, while the atmosphere Δ^(14)C drops. For a very brief interval at ∼12.0 ka and at the end of the Younger Dryas (11.5 ka), intermediate water Δ^(14)C (∼1200 m) approached atmospheric Δ14C. These enriched Δ^(14)C results suggest an enhanced initial Δ^(14)C content of the water and demonstrate the presence of large lateral Δ^(14)C gradients in the intermediate/deep ocean in addition to the sharp vertical shift at ∼2500 m. The transient Δ^(14)C enrichment at ∼12.0 ka occurred in the middle of the Younger Dryas and demonstrates that there is at least one time when the intermediate/deep ocean underwent dramatic change but with much smaller effects in other paleoclimatic records

Synchronous volcanic eruptions and abrupt climate change ∼17.7 ka plausibly linked by stratospheric ozone depletion

Glacial-state greenhouse gas concentrations and Southern Hemisphere climate conditions persisted until ∼17.7 ka, when a nearly synchronous acceleration in deglaciation was recorded in paleoclimate proxies in large parts of the Southern Hemisphere, with many changes ascribed to a sudden poleward shift in the Southern Hemisphere westerlies and subsequent climate impacts. We used high-resolution chemical measurements in the West Antarctic Ice Sheet Divide, Byrd, and other ice cores to document a unique, ∼192-y series of halogen-rich volcanic eruptions exactly at the start of accelerated deglaciation, with tephra identifying the nearby Mount Takahe volcano as the source. Extensive fallout from these massive eruptions has been found >2,800 km from Mount Takahe. Sulfur isotope anomalies and marked decreases in ice core bromine consistent with increased surface UV radiation indicate that the eruptions led to stratospheric ozone depletion. Rather than a highly improbable coincidence, circulation and climate changes extending from the Antarctic Peninsula to the subtropics—similar to those associated with modern stratospheric ozone depletion over Antarctica—plausibly link the Mount Takahe eruptions to the onset of accelerated Southern Hemisphere deglaciation ∼17.7 ka